STRUCTURAL, MAGNETIC AND MOSSBAUER STUDIES OF THE MOLECULAR FERROMAGNET COMPOUNDS NBU(4)[MCR(C2O4)(3)](BU=(CH2)(3)CH3, M=MN, FE)

被引：7

作者：

ATOVMYAN, LO ^{[1
]}

SHILOV, GV ^{[1
]}

OVANESYAN, NS ^{[1
]}

PYALLING, AA ^{[1
]}

LYUBOVSKAYA, RN ^{[1
]}

ZHILYAEVA, EI ^{[1
]}

MOROZOV, YG ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST STRUCT MACROKINET,CHERNOGOLOVKA 142432,RUSSIA

来源：

SYNTHETIC METALS | 1995年 / 71卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(94)03061-A

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

An X-ray study of a single crystal of the NBu(4)[MnCr(C2O4)(3) composition reveals a layered structure with an ordered arrangement of Mn2+ and Cr3+ ions. According to the data of the orientation dependence of magnetization at 4.5K, the magnentic easy axis is aligned along the crystal c-axis. Mossbauer data analysis of isostructural NBu(4)[FeCr(C2O4)(3)] powder material gives, on the contrary, the evidence of strong confinement of Fe2+ spins to the crystal basal plane. The ferromagnetic system which arises here is a quasi-2D system in terms of the nature of its exchange interactions.

引用

页码：1809 / 1810

页数：2