IMAGE-ANALYSIS OF PHASE-SEPARATION IN POLYMERS BLENDS

被引:14
作者
KATZEN, D
REICH, S
机构
[1] Department of Materials and Interfaces, Weizmann Institute of Science, Rehovot
来源
EUROPHYSICS LETTERS | 1993年 / 21卷 / 01期
关键词
D O I
10.1209/0295-5075/21/1/010
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
In this letter we examine experimentally the validity of scaling laws for the dynamics of late stages of phase separation in polystyrene-poly(vinyl methyl ether) thin films. This is done using image analysis, UV transmission microscopy and Nomarsky interferometry. We find that scaling laws do not describe the observed phenomena. Contrary to common belief, the redistribution of the components between the phases persists to the very late stages of the phase separation process. Interfacial surface tension is a dominating force governing the evolution of the observed morphology.
引用
收藏
页码:55 / 60
页数:6
相关论文
共 13 条
[1]   PHASE SEPARATION BY SPINODAL DECOMPOSITION IN ISOTROPIC SYSTEMS [J].
CAHN, JW .
JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (01) :93-+
[2]   DYNAMICS OF FLUCTUATIONS AND SPINODAL DECOMPOSITION IN POLYMER BLENDS [J].
DEGENNES, PG .
JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (09) :4756-4763
[3]   DYNAMIC-SCALING THEORY FOR PHASE-SEPARATING UNMIXING MIXTURES - GROWTH-RATES OF DROPLETS AND SCALING PROPERTIES OF AUTO-CORRELATION FUNCTIONS [J].
FURUKAWA, H .
PHYSICA A, 1984, 123 (2-3) :497-515
[4]   LATE STAGE SPINODAL DECOMPOSITION OF A BINARY POLYMER MIXTURE .1. CRITICAL TEST OF DYNAMIC SCALING ON SCATTERING FUNCTION [J].
HASHIMOTO, T ;
ITAKURA, M ;
HASEGAWA, H .
JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (10) :6118-6128
[5]   LATE STAGE SPINODAL DECOMPOSITION OF A BINARY POLYMER MIXTURE .2. SCALING ANALYSES ON QM(TAU) AND IM(TAU) [J].
HASHIMOTO, T ;
ITAKURA, M ;
SHIMIDZU, N .
JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (11) :6773-6786
[6]   PHASE-SEPARATION OF POLYMER BLENDS IN THIN-FILMS [J].
REICH, S ;
COHEN, Y .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1981, 19 (08) :1255-1267
[7]   PERCOLATION CHARACTERISTICS OF SPINODAL PHASE-SEPARATION IN POLYMER BLENDS [J].
REICH, S .
PHYSICS LETTERS A, 1986, 114 (02) :90-94
[8]   LATE STAGES OF SPINODAL DECOMPOSITION IN BINARY-MIXTURES [J].
SIGGIA, ED .
PHYSICAL REVIEW A, 1979, 20 (02) :595-605
[9]  
SNYDER HL, 1985, J POLYM SCI PS, V73, P213
[10]   TRANSITION FROM METASTABILITY TO INSTABILITY IN A BINARY-LIQUID MIXTURE [J].
TANAKA, H ;
YOKOKAWA, T ;
ABE, H ;
HAYASHI, T ;
NISHI, T .
PHYSICAL REVIEW LETTERS, 1990, 65 (25) :3136-3139