SYNTHESIS AND CHARACTERIZATION OF CORE-SHELL LATEXES WITH MICROSCOPIC AND SOLID-STATE NMR METHODS

被引:12
作者
LANDFESTER, K
BOEFFEL, C
LAMBLA, M
SPIESS, HW
机构
[1] MAX PLANCK INST POLYMER RES,D-55021 MAINZ,GERMANY
[2] CNRS,ECOLE APPLICAT HAUTS POLYMERES,F-67000 STRASBOURG,FRANCE
关键词
SOLID STATE NMR; EMULSION POLYMERIZATION; CORE SHELL LATEXES; ELECTRON MICROSCOPY;
D O I
10.1002/masy.19950920111
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Core-shell latexes based on poly(butylacrylate) and poly(methyl methacrylate) were synthesized with varying shell content at high and low temperature. Electron microscopy combined with advanced solid-state NMR techniques have been used to investigate the entire structure and the interphase morphology in these core-shell particles depending on the reaction conditions. Distinct differences of the interphase morphology were found for particles synthesized at high and low temperature.
引用
收藏
页码:109 / 116
页数:8
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