THE STRUCTURE OF [PDCL2((PY)2(PYH)CH-N',N'')][PDCL4]0.5.2H2O (PY = PYRIDIN-2-YL), A COMPLEX WITH PROTONATED 2,2',2''-METHYLIDYNETRISPYRIDINE AS A BIDENTATE LIGAND

被引：22

作者：

CANTY, AJ ^{[1
]}

MINCHIN, NJ ^{[1
]}

SKELTON, BW ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1992年 / 45卷 / 02期

关键词：

D O I：

10.1071/CH9920423

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystals of dichloro[2,2',2"-methylidynetris(pyridin)-1-ium-N',N"]palladium(II) hemi[tetrachloropalladate(II)] dihydrate are monoclinic, P2(1)/c, a 8.558(5), b 15.516(7), c 16.153(5) angstrom, beta-112.07(4)-degrees, Z 4. The cations [PdCl2{(PY)2(PyH)CH-N',N"}]+ have square-planar geometry for palladium, with the ligand in a boat conformation and having an uncoordinated protonated pyridine group.

引用

页码：423 / 427

页数：5

共 9 条

[1] REVERSIBLE ADDITION OF PROTIC MOLECULES TO COORDINATED DI-2-PYRIDYL KETONE IN PALLADIUM(II), PLATINUM(II), AND GOLD(III) COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF DICHLORO(DIHYDROXY-DI-2-PYRIDYLMETHANE)PALLADIUM(II) AND DICHLORO(DIHYDROXY-DI-2-PYRIDYLMETHANE)GOLD(III) CHLORIDE
ANNIBALE, G
CANOVESE, L
CATTALINI, L
NATILE, G
BIAGINICINGI, M
MANOTTILANFREDI, AM
TIRIPICCHIO, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (12): : 2280 - 2287
[2] COORDINATION CHEMISTRY OF PYRIDYL AND N-METHYLIMIDAZOLYL KETONES - SYNTHETIC AND X-RAY STRUCTURAL STUDIES OF COPPER(II), NICKEL(II), AND DIMETHYLGOLD(III) COMPLEXES
BYERS, PK
CANTY, AJ
ENGELHARDT, LM
PATRICK, JM
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (05): : 981 - 986
[3] COORDINATION CHEMISTRY OF DIMETHYLGOLD(III) - SYNTHESIS, STRUCTURAL STUDIES, AND FLUXIONAL BEHAVIOR OF COMPLEXES WITH POLYDENTATE LIGANDS
BYERS, PK
CANTY, AJ
MINCHIN, NJ
PATRICK, JM
SKELTON, BW
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (06): : 1183 - 1189
[4] COORDINATION CHEMISTRY OF DIMETHYLGOLD(III) AND METHYLMERCURY(II) - SYNTHESIS, H-1-NMR AND STRUCTURAL STUDIES OF POLY(PYRAZOL-1-YL)BORATE COMPLEXES
CANTY, AJ
MINCHIN, NJ
PATRICK, JM
WHITE, AH
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1983, 36 (06) : 1107 - 1113
[5] INTERACTION OF PALLADIUM(II) WITH POLYDENTATE LIGANDS, INCLUDING THE SYNTHESIS AND STRUCTURE OF BIS[TRIS(PYRAZOL-1-YL)BORATO-N,N']PALLADIUM(II) AND THE CATIONS [PD(L)2]2+ [L=TRIS(PYRAZOL-1-YL)METHANE-N,N' OR TRIS(PYRIDIN-2-YL)METHANE-N,N']
CANTY, AJ
MINCHIN, NJ
ENGELHARDT, LM
SKELTON, BW
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (03): : 645 - 650
[6] COORDINATION CHEMISTRY OF DIMETHYLGOLD(III) - SYNTHESIS, SPECTROSCOPIC, AND STRUCTURAL STUDIES OF COMPLEXES WITH NEUTRAL AROMATIC NITROGEN-DONOR LIGANDS
CANTY, AJ
MINCHIN, NJ
HEALY, PC
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (09): : 1795 - 1802
[7] HALL SR, 1990, XTAL USERS MANUAL VE
[8] Ibers J. A., 1974, INT TABLES XRAY CRYS, VIV
[9] BIS(2-PYRIDYL)SILANE LIGANDS .2. STRUCTURAL CHARACTERIZATION AND CATALYTIC APPLICATIONS OF PALLADIUM COMPLEXES IN ORGANOSTANNANE CROSS-COUPLING REACTIONS
WRIGHT, ME
LOWEMA, CK
[J]. ORGANOMETALLICS, 1990, 9 (02) : 347 - 352

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