VERSATILE ENZYMATIC DIACID ESTER SYNTHESIS OF BUTYL DELTA-D-GLUCOPYRANOSIDE

被引：11

作者：

FABRE, J

BETBEDER, D

PAUL, F

MONSAN, P

PERIE, J

机构：

[1] BIOEUROPE,4 IMPASSE DIDIER DAURAT,BP 4196,F-31031 TOULOUSE,FRANCE

[2] UNIV TOULOUSE 3,CHIM ORGAN BIOL LAB,CNRS,URA 470,F-31062 TOULOUSE,FRANCE

来源：

TETRAHEDRON | 1993年 / 49卷 / 47期

关键词：

D O I：

10.1016/S0040-4020(01)80240-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enzymatic esterification of butyl alpha-D-glucopyranoside by diacids was investigated with pig pancreatic lipase in acetone. The nature of the acylating agent influenced the regiospecificity of the reaction. A chemoenzymatic reaction scheme was developed to obtain diacid esters using an activated diacid as acyl donor, in a solvent-free process with the immobilized lipase of Mucor miehei (Lipozyme(R)).

引用

收藏

页码：10877 / 10882

页数：6

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