ACID MEDIATED INTRAMOLECULAR CYCLIZATION OF PI-DONORS BEARING 2 VICINAL CIS-BRANCHED, 1,4-DITHIAFULVEN-6-YL SUBSTITUENTS ON A C=C BOND

被引：22

作者：

BENAHMEDGASMI, AS

FRERE, P

BELYASMINE, A

MALIK, KMA

HURSTHOUSE, MB

MOORE, AJ

BRYCE, MR

JUBAULT, M

GORGUES, A

机构：

[1] UNIV ANGERS,CHIM ORGAN FONDAMENTALE & APPLIQUEE LAB,2 BD LAVOISIER,F-49045 ANGERS,FRANCE

[2] UNIV ORAN,CHIM ORGAN LAB,ORAN,ALGERIA

[3] UNIV WALES COLL CARDIFF,SCH CHEM & APPL CHEM,CARDIFF CF1 3TB,WALES

[4] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 13期

关键词：

PI-DONORS; TETRATHIAFULVALENE (TTF) ANALOGS; ORGANIC CONDUCTORS; WITTIG(-HORNER) REACTIONS; INTRAMOLECULAR CYCLIZATIONS;

D O I：

10.1016/S0040-4039(00)60363-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cis-ethylenic analogues 1 and ortho-benzenic analogues 2 of TTF undergo a rapid acid mediated intramolecular cyclization into the corresponding cycloisomers 1' and 2' whose structures are confirmed by X-ray diffraction; as shown by cyclic voltammetry, compounds 1 may act as convenient precursors of organic metals.

引用

页码：2131 / 2134

页数：4

共 23 条

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