SYNTHESIS AND X-RAY STRUCTURAL CHARACTERIZATION OF A NOVEL OXYFLUORINATED MICROPOROUS GALLIUM PHOSPHATE WITH ENCAPSULATED 1,4-DIAZABICYCLO[2.2.2]OCTANE AS THE TEMPLATE - GA3(PO4)(HPO4)2F3(OH).C6N2H14.0.5 H2O

被引:58
作者
LOISEAU, T [1 ]
FEREY, G [1 ]
机构
[1] UNIV MAINE,FAC SCI,FLUORURES LAB,CNRS,URA 449,AVE OLIVIER MESSIAEN,F-72017 LE MANS,FRANCE
关键词
D O I
10.1039/c39920001197
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A gallophosphate with an open framework is synthesized; its structure consists of interconnecting Ga2O7-PHI-F2 (PHI = O or OH) bioctahedra and PO4 tetrahedra, building up a three-dimensional network around a novel (3(12)6(4)8(8)) cage type, enclosing two 1,4-diazabicyclo[2.2.2]octane organic templates and leading to eight-membered channels along [001], six- and eight-rings along [101] and [010], the water molecule being located in the latter.
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页码:1197 / 1198
页数:2
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