SYNTHESIS, CRYSTAL DATA AND THERMAL-STABILITY OF MAGNESIUM ZIRCONIUM-PHOSPHATE [MGZR4(PO4)6]

被引：26

作者：

KAZAKOSKIJOWSKI, A

KOMARNENI, S

AGRAWAL, D

ROY, R

机构：

[1] Pennsylvania State University,, University Park, PA, USA, Pennsylvania State University, University Park, PA, USA

来源：

MATERIALS RESEARCH BULLETIN | 1988年 / 23卷 / 08期

关键词：

CRYSTALS; -; Structure; ELECTROLYTES; SOLID - Synthesis - GELS - Precipitation - PHOSPHATES - Thermal Properties - SOLIDS - Ionic Conduction;

D O I：

10.1016/0025-5408(88)90209-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The synthesis of MgZr//4(PO//4)//6 by a sol-gel method is described, and the thermal stability of this low-thermal-expansion material is presented. Crystal data were calculated from powder X-ray diffraction data, which show this phase to be monoclinic primitive with cell parameters a equals 12. 426 angstrom, b equals 8. 836 angstrom, c equals 8. 903 angstrom, and beta equals 89. 62 degree .

引用

页码：1177 / 1184

页数：8

共 17 条

[1] SYNTHESIS AND SINTERING OF CA0.5ZR2P3O12-A LOW THERMAL-EXPANSION MATERIAL [J].

AGRAWAL, DK ;

STUBICAN, VS .

MATERIALS RESEARCH BULLETIN, 1985, 20 (02) :99-106

[2] ULTRALOW-EXPANSION CERAMICS IN THE SYSTEM NA2O-ZRO2-P2O5-SIO2 [J].

ALAMO, J ;

ROY, R .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1984, 67 (05) :C78-C80

[3] PHASE-TRANSFORMATION IN NA1+XSIXZR2P3-XO12 COMPOUNDS [J].

BOILOT, JP ;

SALANIE, JP ;

DESPLANCHES, G ;

LEPOTIER, D .

MATERIALS RESEARCH BULLETIN, 1979, 14 (11) :1469-1477

[4] PREPARATION OF (NH4)ZR2(PO4)3 AND HZR2(PO4)3 [J].

CLEARFIELD, A ;

ROBERTS, BD ;

SUBRAMANIAN, MA .

MATERIALS RESEARCH BULLETIN, 1984, 19 (02) :219-226

[5] FAST NA+-ION TRANSPORT IN SKELETON STRUCTURES [J].

GOODENOUGH, JB ;

HONG, HYP ;

KAFALAS, JA .

MATERIALS RESEARCH BULLETIN, 1976, 11 (02) :203-220

[6]

GOULD W, UNPUB J SOLID STATE

[7] CRYSTAL-STRUCTURES AND CRYSTAL-CHEMISTRY IN SYSTEM NA1+XZR2SIXP3-XO12 [J].

HONG, HYP .

MATERIALS RESEARCH BULLETIN, 1976, 11 (02) :173-182

[8] SOLID ELECTROLYTES WITH MULTIVALENT CATION CONDUCTION .1. CONDUCTING SPECIES IN MG-ZR-PO4 SYSTEM [J].

IKEDA, S ;

TAKAHASHI, M ;

ISHIKAWA, J ;

ITO, K .

SOLID STATE IONICS, 1987, 23 (1-2) :125-129

[9] THERMAL-EXPANSION OF NH4ZR2(PO4)3 [J].

KOMARNENI, S ;

LENAIN, GE ;

ROY, R .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1986, 5 (01) :1-3

[10]

KOMARNENI S, 1987, 87 INT S EXHIBITION, P420

← 1 2 →