THE MAGNETIC CIRCULAR-DICHROISM AND ABSORPTION-SPECTRA OF C60 ISOLATED IN AR MATRICES

被引：127

作者：

GASYNA, Z ^{[1
]}

SCHATZ, PN ^{[1
]}

HARE, JP ^{[1
]}

DENNIS, TJ ^{[1
]}

KROTO, HW ^{[1
]}

TAYLOR, R ^{[1
]}

WALTON, DRM ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 183卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(91)80064-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The absorption and magnetic circular dichroism (MCD) spectra of C60 isolated in Ar matrices have been measured in the visible and near-ultraviolet. The first two allowed bands (at almost-equal-to 326 and almost-equal-to 253 nm) show substantial negative .d terms. Sharp, weak vibronic structure showing clear evidence of Jahn-Teller activity is observed in both the 400 and 600 nm regions. Detailed assignments are proposed for the resolved spectral features.

引用

页码：283 / 291

页数：9

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