FLUORINATION OF C6F5MX3 COMPOUNDS (M=SI, GE, X=F, CL, BR, ALK) WITH XENON DIFLUORIDE AND XEF+ Y- SALTS

被引：18

作者：

BARDIN, VV ^{[1
]}

FROHN, HJ ^{[1
]}

机构：

[1] UNIV DUISBURG GESAMTHSCH,DEPT INORGAN CHEM,W-4100 DUISBURG 1,GERMANY

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 60卷 / 2-3期

关键词：

D O I：

10.1016/S0022-1139(00)80028-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Compounds of the formula C6F5MX3 (M = Si, Ge; X = Cl, Br) react with XeF2, exchanging chlorine (bromine) atoms for fluorine. Interaction of C6F5MX3 (X = F, Alk) with XeF2 in the presence of BF3 . OEt2 or with XeF+ NbF6- proceeds by the addition of two fluorine atoms to the pentafluorophenyl ring.

引用

页码：141 / 151

页数：11

共 26 条

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