OXIDATION WITH PERHALOGENATED, WATER-SOLUBLE METALLOPORPHYRINS - APPLICATION TO OXIDATION OF SUBSTITUTED 2-METHYLPYRROLES

被引：8

作者：

KARUNARATNE, V ^{[1
]}

DOLPHIN, D ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER,BC V6T 1Z1,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 20期

关键词：

D O I：

10.1039/c39950002105

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Perchlorinated, sulfonated metalloporphyrin 1 cleanly oxidized substituted 2-methylpyrroles 2a-f in the presence of iodosylbenzene to produce the corresponding allylic alcohols 3a-f.

引用

页码：2105 / 2106

页数：2

共 14 条

[1]

BARLOY L, 1992, NEW J CHEM, V61, P71

[2] NIH SHIFT IN HAEMIN-IODOSYLBENZENE-MEDIATED HYDROXYLATIONS [J].

CHANG, CK ;

EBINA, F .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (15) :778-779

[3]

DEMONTELLANO PRO, 1986, CYTOCHROME P450 STRU, P217

[4] HYDROXYLATION AND EPOXIDATION CATALYZED BY IRON-PORPHINE COMPLEXES - OXYGEN-TRANSFER FROM IODOSYLBENZENE [J].

GROVES, JT ;

NEMO, TE ;

MYERS, RS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (04) :1032-1033

[5] CHEMICAL MECHANISMS OF CATALYSIS BY CYTOCHROMES-P-450 - A UNIFIED VIEW [J].

GUENGERICH, FP ;

MACDONALD, TL .

ACCOUNTS OF CHEMICAL RESEARCH, 1984, 17 (01) :9-16

[6]

JORGENSEN KA, 1989, CHEM REV, V89, P431

[7]

MINOUN H, 1980, J MOL CATAL, V7, P1

[8]

NAKANO T, 1990, Patent No. 4892241

[9]

Sharpless K. B., 1979, ALDRICHIM ACTA, V12, P63

[10]

Sheldon R. A., 1981, METAL CATALYZED OXID

← 1 2 →