COLLECTION OF ION-TRAP MASS-SPECTRA OF SULFONYLUREA PYROLYSIS PRODUCTS

被引:2
作者
GALLETTI, GC
DINELLI, G
CHIAVARI, G
机构
[1] UNIV BOLOGNA,DEPT AGRON,I-40126 BOLOGNA,ITALY
[2] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY
来源
JOURNAL OF MASS SPECTROMETRY | 1995年 / 30卷 / 02期
关键词
D O I
10.1002/jms.1190300216
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The pyrograms of 14 sulfonylureas, i.e. herbicides characterized by high biological activity and low application dose are discussed and the mass spectra of over 30 relevant pyrolysis products as obtained with a heated filament pyrolyzer interfaced to a capillary gas chromatograph/ion-trap detector mass spectrometer are presented. Such a data compilation is useful for diagnostic purposes for both intact sulfonylureas and their metabolites after degradation in soil, because metabolites and pyrolysis products are often identical and most of their mass spectra are lacking in commercially available mass spectral libraries. The performance of the ion-trap detector based on the qualify of the mass spectra is briefly discussed.
引用
收藏
页码:333 / 338
页数:6
相关论文
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