CHARACTERIZATION AND APPLICATION OF A NEW DIPROTECTED CYCLAM - A NOVEL 2-STEP SYNTHESIS OF LINKED TETRAAZAMACROCYCLES

被引：42

作者：

BOITREL, B ^{[1
]}

ANDRIOLETTI, B ^{[1
]}

LACHKAR, M ^{[1
]}

GUILARD, R ^{[1
]}

机构：

[1] CNRS,SYNTH & ELECTROSYNTH ORGANOMET LAB,F-21100 DIJON,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 28期

关键词：

CYCLAM; GENERAL SYNTHESIS; COFACIAL STRUCTURE; PROTECTIVE GROUP;

D O I：

10.1016/00404-0399(50)09312-

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and separation of the 1,8-di-(tertbutyloxycarbonyl) cyclam (1,8-diboc cyclam) among other isomers allow the facile obtention of singly or doubly linked, and bridged tetraazamacrocycles within a two-step synthesis in a very convenient way. This strategy can be applied to a large scale preparation of several types of dioxygen carriers or activators.

引用

页码：4995 / 4998

页数：4

共 15 条

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