CHARACTERIZATION AND APPLICATION OF A NEW DIPROTECTED CYCLAM - A NOVEL 2-STEP SYNTHESIS OF LINKED TETRAAZAMACROCYCLES

被引:42
作者
BOITREL, B [1 ]
ANDRIOLETTI, B [1 ]
LACHKAR, M [1 ]
GUILARD, R [1 ]
机构
[1] CNRS,SYNTH & ELECTROSYNTH ORGANOMET LAB,F-21100 DIJON,FRANCE
关键词
CYCLAM; GENERAL SYNTHESIS; COFACIAL STRUCTURE; PROTECTIVE GROUP;
D O I
10.1016/00404-0399(50)09312-
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis and separation of the 1,8-di-(tertbutyloxycarbonyl) cyclam (1,8-diboc cyclam) among other isomers allow the facile obtention of singly or doubly linked, and bridged tetraazamacrocycles within a two-step synthesis in a very convenient way. This strategy can be applied to a large scale preparation of several types of dioxygen carriers or activators.
引用
收藏
页码:4995 / 4998
页数:4
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