THE VISCOSITY OF GASEOUS ETHANE AND ITS INITIAL DENSITY DEPENDENCE

被引:29
作者
HENDL, S
VOGEL, E
机构
[1] Universität Rostock, Fachbereich Chemie, Rostock 1, D-0-2500
关键词
CORRELATION; ETHANE; POLYATOMIC GAS; 2ND VISCOSITY VIRAL COEFFICIENT; TRANSPORT PROPERTY; VISCOSITY;
D O I
10.1016/0378-3812(92)85093-N
中图分类号
O414.1 [热力学];
学科分类号
摘要
New high-precision measurements of the viscosity-eta of gaseous ethane from near room temperature up to 630 K and at densities between 0.3 and 1.6 kg-m-3 and between 0.01 and 0.05 mol.L-1, respectively, carried out in an all-quartz oscillating-disk viscometer with small gaps are reported. The data for the viscosity of ethane at 0.1013 MPa are in good agreement with other high-precision experimental data from literature near room temperature. Additionally, the new experimental data were used to create an individual correlation of the zero-density viscosity coefficient. Only positive values with a maximum in the middle of the temperature range were found for the second viscosity virial coefficient B(eta). These results corroborate the Rainwater-Friend (1984) theory and the recent investigation by Bich and Vogel (1991).
引用
收藏
页码:259 / 272
页数:14
相关论文
共 43 条
[1]   VISCOSITY AND DIFFUSION-COEFFICIENTS OF MIXTURES OF 4 LIGHT-HYDROCARBON GASES [J].
ABE, Y ;
KESTIN, J ;
KHALIFA, HE ;
WAKEHAM, WA .
PHYSICA A, 1978, 93 (1-2) :155-170
[2]  
Adzumi H., 1937, B CHEM SOC JPN, V12, P199
[3]  
[Anonymous], 1987, INTERMOLECULAR FORCE
[4]   THE INITIAL DENSITY DEPENDENCE OF TRANSPORT-PROPERTIES - NOBLE-GASES [J].
BICH, E ;
VOGEL, E .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1991, 12 (01) :27-42
[5]  
BICH E, 1987, WISS Z W PIECK U ROS, V36, P5
[6]  
Carmichael L. T., 1963, J CHEM ENG DATA, V8, P94
[7]   THE VISCOSITIES OF ORGANIC VAPOURS [J].
CRAVEN, PM ;
LAMBERT, JD .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1951, 205 (1082) :439-449
[8]   INTERMOLECULAR POTENTIALS OF ARGON, METHANE, AND ETHANE [J].
DEROCCO, AG ;
HALFORD, JO .
JOURNAL OF CHEMICAL PHYSICS, 1958, 28 (06) :1152-1154
[9]  
Eakin B.E., 1962, J CHEM ENG DATA, V7, P33
[10]  
ENSKOG D, 1922, KGL SVENSKA VENTENSK, V63