A NOVEL SUPERMETASTABLE WO3 PHASE

被引:25
作者
SEGUIN, L
FIGLARZ, M
PANNETIER, J
机构
[1] UNIV PICARDIE JULES VERNE,REACTIV & CHIM SOLIDES LAB,CNRS,URA 1211,33 RUE ST LEU,F-80039 AMIENS,FRANCE
[2] INST MAX VON LAUE PAUL LANGEVIN,F-38042 GRENOBLE,FRANCE
关键词
D O I
10.1016/0167-2738(93)90141-O
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new WO3 phase has been identified by X-ray and neutron diffraction studies, heating infrared spectroscopy, DSC and TG analysis. This new phase, obtained from the dehydration of WO3.1/3H2O, has a free energy greater than that of the metastable hexagonal WO3. The X-ray powder diffractogram of this supermetastable phase is the same as that of the hydrate oxide.
引用
收藏
页码:437 / 441
页数:5
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