LASER-BASED FLAME SPECIES PROFILE MEASUREMENTS - A COMPARISON WITH FLAME MODEL PREDICTIONS

被引：51

作者：

BERNSTEIN, JS ^{[1
]}

FEIN, A ^{[1
]}

CHOI, JB ^{[1
]}

COOL, TA ^{[1
]}

SAUSA, RC ^{[1
]}

HOWARD, SL ^{[1
]}

LOCKE, RJ ^{[1
]}

MIZIOLEK, AW ^{[1
]}

机构：

[1] USA,BALLIST RES LABS,ABERDEEN PROVING GROUND,MD 21005

来源：

COMBUSTION AND FLAME | 1993年 / 92卷 / 1-2期

关键词：

D O I：

10.1016/0010-2180(93)90200-M

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Two laser-based diagnostic methods, resonance-enhanced multiphoton ionization (REMPI) and laser-induced fluorescence (LIF), were used for relative concentration measurements of seven species, O, H, OH, CH, CO, HCO, and CH3, in low pressure stoichiometric methane/oxygen, ethylene/oxygen, and ethane/oxygen premixed hydrocarbon flames. For the well-understood methane/oxygen flame, measured relative density profiles for these seven species were in good agreement with flame modeling calculations. This agreement justifies the use of the stoichiometric methane/oxygen flame as a standard of comparison by which relative density profiles, measured for other hydrocarbon flames, may be placed on an absolute density scale. This approach was applied to measurements for the ethylene/oxygen and ethane/oxygen flames. Peak HCO densities for these flames appear to be overestimated by model calculations based on current kinetic models of C1 and C2 chemistry.

引用

页码：85 / 105

页数：21

共 57 条

[1] ALDEN M, COMMUNICATION
[2] ABSOLUTE 2-PHOTON ABSORPTION AND 3-PHOTON IONIZATION CROSS-SECTIONS FOR ATOMIC OXYGEN
BAMFORD, DJ
JUSINSKI, LE
BISCHEL, WK
[J]. PHYSICAL REVIEW A, 1986, 34 (01): : 185 - 198
[3] ATMOSPHERIC-PRESSURE PREMIXED HYDROCARBON-AIR FLAMES - THEORY AND EXPERIMENT
BECHTEL, JH
BLINT, RJ
DASCH, CJ
WEINBERGER, DA
[J]. COMBUSTION AND FLAME, 1981, 42 (02) : 197 - 213
[4] BECHTEL JH, 1983, LASER APPLICATIONS
[5] Benson, 1976, THERMOCHEMICAL KINET, V23, P613
[6] DETECTION OF THE FORMYL RADICAL IN A METHANE OXYGEN FLAME BY RESONANCE IONIZATION
BERNSTEIN, JS
SONG, XM
COOL, TA
[J]. CHEMICAL PHYSICS LETTERS, 1988, 145 (03) : 188 - 192
[7] MOLECULAR-BEAM MASS-SPECTROMETRY FOR STUDYING FUNDAMENTAL CHEMISTRY OF FLAMES
BIORDI, JC
[J]. PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 1977, 3 (03) : 151 - 173
[8] BIORDI JC, 1975, 15TH S INT COMB PITT, P917
[9] QUENCHING OF 2-PHOTON-EXCITED H(3S, 3D) AND O(3P 3P2,1,0) ATOMS BY RARE-GASES AND SMALL MOLECULES
BITTNER, J
KOHSEHOINGHAUS, K
MEIER, U
JUST, T
[J]. CHEMICAL PHYSICS LETTERS, 1988, 143 (06) : 571 - 576
[10] KINETIC MECHANISMS FOR PREMIXED, LAMINAR, STEADY-STATE METHANE AIR FLAMES
COFFEE, TP
[J]. COMBUSTION AND FLAME, 1984, 55 (02) : 161 - 170

← 1 2 3 4 5 6 →