RAMAN-SPECTRA OF VATERITIC CALCIUM-CARBONATE

被引：117

作者：

BEHRENS, G ^{[1
]}

KUHN, LT ^{[1
]}

UBIC, R ^{[1
]}

HEUER, AH ^{[1
]}

机构：

[1] CASE WESTERN RESERVE UNIV,DEPT MAT SCI & ENGN,CLEVELAND,OH 44106

来源：

SPECTROSCOPY LETTERS | 1995年 / 28卷 / 06期

基金：

美国国家卫生研究院;

关键词：

RAMAN SPECTROSCOPY; VATERITE; CALCITE; ARAGONITE; CRYSTALLOGRAPHY;

D O I：

10.1080/00387019508009934

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The Raman spectrum of polycrystalline vaterite is presented and compared to spectra of calcite and aragonite, the other two common CaCO3 polymorphs; Raman spectroscopy easily distinguishes between these three polymorphs. An important feature of the Raman spectrum of vaterite is splitting of both the vl and v(4) peaks. The splitting of the v(1) peak implies two distinct site symmetries for the CO3-2 groups. A definitive crystal structure determination of vaterite is not yet available, but none of the three proposed structures for vaterite show such a feature.

引用

页码：983 / 995

页数：13

共 13 条

[1] ADLER HH, 1963, AM MINERAL, V48, P839
[2] ADLER HH, 1962, AM MINERAL, V47, P700
[3] VATERITE-TYPE ABO3 RARE-EARTH BORATES
BRADLEY, WF
GRAF, DL
ROTH, RS
[J]. ACTA CRYSTALLOGRAPHICA, 1966, 20 : 283 - &
[4] COUTURE L, 1947, ANN PHYS, V0017, P00088
[5] FERRARO JR, 1969, INTRO GROUP THEORY
[6] RAMAN STUDIES ON ROCK-FORMING MINERALS .2. MINERALS CONTAINING MO3, MO4, AND MO6 GROUPS
GRIFFITH, WP
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (02): : 286 - +
[7] ON STRUCTURE OF VATERITE, CACO3
KAMHI, SR
[J]. ACTA CRYSTALLOGRAPHICA, 1963, 16 (08): : 770 - &
[8] Lippmann F., 1973, SEDIMENTARY CARBONAT
[9] STRUCTURE AND DISORDER IN VATERITE
MEYER, HJ
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE KRISTALLGEOMETRIE KRISTALLPHYSIK KRISTALLCHEMIE, 1969, 128 (3-6): : 183 - &
[10] OPTICALLY ACTIVE CRYSTAL VIBRATIONS OF ALKALI-METAL NITRATES
NAKAGAWA, I
WALTER, JL
[J]. JOURNAL OF CHEMICAL PHYSICS, 1969, 51 (04) : 1389 - +

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