INTRINSIC SELECTIVITY AND ITS GEOMETRIC SIGNIFICANCE IN SN2 REACTIONS

被引：12

作者：

SHAIK, SS

机构：

[1] Department of Chemistry, Ben Gurion University, Beer Sheva,84105, Israel

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1986年 / 64卷 / 01期

关键词：

D O I：

10.1139/v86-016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An intrinsic selectivity is defined for identity SN2 reactions (X- + RX → XR + X-). This selectivity parameter is shown to yield information about: (a) the average looseness of the TS geometry in a reaction series; and (b) the sensitivity of the reaction series to geometric loosening.

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页码：96 / 99

页数：4

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