REDUCTION OF AROMATIC-COMPOUNDS IN ORGANIC CHLOROALUMINATE MELTS .2. PERYLENE

被引：3

作者：

COFFIELD, JE ^{[1
]}

MAMANTOV, G ^{[1
]}

ZINGG, SP ^{[1
]}

SMITH, GP ^{[1
]}

BUCHANAN, AC ^{[1
]}

机构：

[1] OAK RIDGE NATL LAB,DIV CHEM,OAK RIDGE,TN 37831

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1992年 / 139卷 / 02期

关键词：

D O I：

10.1149/1.2069220

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electroreduction of perylene in basic mixtures of AlCl3 and 1-ethyl-3-methyl-1H-imidazolium chloride (44.4 mol % AlCl3) as well as 1,2-dimethyl-3-propyl-1H-imidazolium chloride (47.4 mol % AlCl3) has been investigated by electrochemical, spectroscopic, and spectroelectrochemical techniques. The reduction of perylene proceeds through an ECEC process with the likely product being the aluminum chloride adduct of the dianion of perylene. In addition, a radical anion intermediate has been identified and its rate of decay measured.

引用

页码：355 / 359

页数：5

共 36 条

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[2]

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[3]

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[4]

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