MAGNETIC PROBING OF TRANSITION-STATES

被引：2

作者：

BUCHACHENKO, AL ^{[1
]}

TARASOV, VF ^{[1
]}

GHATLIA, ND ^{[1
]}

TURRO, NJ ^{[1
]}

机构：

[1] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 192卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(92)85443-E

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The concept of dynamic trajectories on the potential energy surface of magnetic and exchange interactions for cage reactions in a radical pair is formulated. The magnetic effects induced by static as well as by a combination of static and radiowave magnetic fields are considered as tools for magnetic probing of the exchange potential along the dissociating bond. Transition state radio-spectroscopy as an analogue to the transition state femtosecond spectroscopy, developed by Zewail, is suggested.

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页码：139 / 144

页数：6

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