GAS-PHASE REACTIONS OF M+ AND [CPM]+ (M = FE, CO, NI) WITH 1,3,5-TRISILACYCLOHEXANE - 1ST EVIDENCE FOR THE FORMATION OF 1,3,5-TRISILABENZENE

被引：14

作者：

BJARNASON, A ^{[1
]}

ARNASON, I ^{[1
]}

机构：

[1] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19718

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 12期

关键词：

D O I：

10.1002/anie.199216331

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Preferential elimination of HD in the gas-phase reactions of [CpM]+, M = Fe, Co, Ni, with deuterated trisilacyclohexane 1 points to the formation of trisilabenzene, previously unknown, as a ligand. The results of collision experiments also support the formation of 2 (deuterated) in these reactions.

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页码：1633 / 1634

页数：2

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