CORRELATION OF X-RAY CRYSTAL-STRUCTURES OF CHIRAL BISPHOSPHINE-RHODIUM CATALYSTS AND THE ABSOLUTE-CONFIGURATION OF THE PRODUCTS RESULTED BY THEIR ASYMMETRIC HYDROGENATIONS

被引：29

作者：

SAKURABA, S ^{[1
]}

MORIMOTO, T ^{[1
]}

ACHIWA, K ^{[1
]}

机构：

[1] UNIV SHIZUOKA,SCH PHARMACEUT SCI,395 YADA,SHIZUOKA 422,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)86111-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chiral positioning array (P/M-chirality) of four phenyl rings in the rhodium-chiral bisphosphine catalyst has been revealed to play an important role in determining the absolute configuration of the asymmetric hydrogenation product.

引用

页码：597 / 600

页数：4

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