GAS-PHASE SUBSTITUENT EFFECT ON BASICITY OF PHENYLACETYLENE - INTRINSIC RESONANCE DEMAND OF PHENYLVINYL CATION

被引：16

作者：

MISHIMA, M

ARIGA, T

FUJIO, M

TSUNO, Y

KOBAYASHI, S

TANIGUCHI, H

机构：

[1] KYUSHU UNIV, FAC SCI, DEPT CHEM, HIGASHI KU, FUKUOKA 812, JAPAN

[2] KYUSHU UNIV, FAC ENGN, DEPT APPL CHEM, HIGASHI KU, FUKUOKA 812, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 06期

关键词：

D O I：

10.1246/cl.1992.1085

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The substituent effect on gas-phase basicity of phenylacetylene has been analyzed in terms of the LArSR Eq., providing an r of 1.21 and a rho of -14.1. The magnitude of the r is reconciled with the "resonance demand - carbocation stability relation" derived from sp2-hybridized benzylic carbocations.

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页码：1085 / 1088

页数：4

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