NEW COORDINATION MODE OF 4,5-DIMERCAPTO-1,3-DITHIOLE-2-THIONATE(2-) IN POLYNUCLEAR GOLD(I) COMPLEXES - CRYSTAL-STRUCTURES OF [AU3(MU(3)-C3S5)(PPH3)3]CLO4 AND [AU4(MU-C3S5)2(MU-PH2PCH2PPH2)2]

被引：29

作者：

CERRADA, E

LAGUNA, A

LAGUNA, M

JONES, PG

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN

[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 08期

关键词：

D O I：

10.1039/dt9940001325

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ligand 4,5-dimercapto-1,3-dithiole-2-thionate(2-) (C3S52-) has been transferred from [NEt4]2-[Zn(C3S5)2] to gold(I) centres. affording di-, tri- or tetra-nuclear complexes containing the C3S52- ligand in unprecedented mu- or mu3-bridging forms.

引用

页码：1325 / 1326

页数：2

共 17 条

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