CONTROL OF NUCLEOPHILIC REGIOCHEMISTRY BY THE DIENE CONFORMATION - DEVELOPMENT OF SYNTHETIC APPLICATION FOR UNSTABLE 2-CARBOXYLATED 1,3-DIENES

被引：9

作者：

CHENG, MH

HO, YH

LEE, GH

PENG, SM

LIU, RS

机构：

[1] NATL TSINGHUA UNIV,DEPT CHEM,HSINCHU 30043,TAIWAN

[2] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 10期

关键词：

D O I：

10.1039/c39910000697

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tungsten-eta-4-carboxylated-1,3-diene cations in both s-trans and s-cis forms have been prepared and the influence of the diene conformation on its nucleophilic regiochemistry is demonstrated; the synthetic utility of these diene complexes is reported, and the crystal structure of one product has been determined.

引用

收藏

页码：697 / 698

页数：2

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