(DIALKYLSULFIDE)(ARENE)RUTHENIUM(II) DERIVATIVES

被引：16

作者：

GAYE, M ^{[1
]}

DEMERSEMAN, B ^{[1
]}

DIXNEUF, PH ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM COORDINAT ORGAN LAB,CNRS,URA 415,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 411卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)86026-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparations are reported of neutral and cationic (dialkylsufide)(eta-6-arene)ruthenium(II) complexes of the types (eta-6-arene)Cl2Ru(SR2), [(eta-6-arene)ClRu(SR2)2]+ and [(eta-6-arene)ClRu(SR2)(L)]+. These complexes containing labile R2S-Ru bonds can be used in the ready generation of 16 electron ruthenium moieties for the activation of terminal alkynes and access to cationic (carbene)(eta-6-arene)ruthenium(II) derivatives such as {(1,3,5-Me3C6H3)ClRu(SMe2)[C(OMe)CH2Ph]}+ and {(C6Me6)ClRu(PMe3)[C(OMe)CH2Ph]}+.

引用

页码：263 / 270

页数：8

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