N-ACYL-1-CHLORO-2,2,2-TRIFLUOROETHYLAMINE AS A 2,2,2-TRIFLUOROETHYLAMINE-BUILDING BLOCK

被引：10

作者：

TANAKA, K

ISHIGURO, Y

MITSUHASHI, K

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 02期

关键词：

D O I：

10.1246/bcsj.66.661

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of N- benzoyl- and N-acetyl-1-chloro-2,2,2-trifluoroethylamines with various carbon-nucleophiles gave the corresponding I-substituted N-acyl-2,2,2-trifluoroethylamines in good yields and the efficient reactivity was applied on the synthesis of 2-acylamiiio-2-trifluoromethylethanol derivative.

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页码：661 / 663

页数：3

相关论文

共 11 条

[1] REINVESTIGATION OF THE PICTET-GAMS ISOQUINOLINE SYNTHESIS .1. CONSEQUENCES OF OXAZOLINE RATHER THAN ISOQUINOLINE FORMATION [J].

ARDABILCHI, N ;

FITTON, AO ;

FROST, JR ;

OPPONGBOACHIE, FK ;

HADI, AHBA ;

SHARIF, AM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (02) :539-543

[2]

BEGUE JP, 1989, SYNTHESIS-STUTTGART, P309

[3] FLUORINE-CONTAINING NITROGEN COMPOUNDS .1. TRIFLUOROETHYLAMINES [J].

BISSELL, ER ;

FINGER, M .

JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (09) :1256-1259

[4]

FUCHIGAMI T, 1987, J ORG CHEM, V52, P5491

[5] DESIGN OF CHIRAL DERIVATIZING AGENTS FOR CHROMATOGRAPHIC RESOLUTION OF OPTICAL ISOMERS - ASYMMETRIC SYNTHESIS OF SOME CHIRAL FLUOROALKYLATED AMINES [J].

PIRKLE, WH ;

HAUSKE, JR .

JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (14) :2436-2439

[6] SYNTHESIS OF TRIFLUOROMETHYL AZOLES USING BUILDING-BLOCKS [J].

TANAKA, K ;

MITSUHASHI, K .

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1987, 45 (03) :269-283

[7] SYNTHESIS OF TRIFLUOROMETHYLTHIAZOLES AND THEIR APPLICATION TO AZO DYES [J].

TANAKA, K ;

NOMURA, K ;

ODA, H ;

YOSHIDA, S ;

MITSUHASHI, K .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1991, 28 (04) :907-911

[8] NOVEL APPLICATIONS OF THE TERT-AMINO EFFECT IN HETEROCYCLIC CHEMISTRY - SYNTHESIS OF A PYRROLO[1,2-A]QUINAZOLINE AND 5H-PYRROLO[1,2-A][3,1]BENZOTHIAZINES [J].

VERBOOM, W ;

HAMZINK, MRJ ;

REINHOUDT, DN ;

VISSER, R .

TETRAHEDRON LETTERS, 1984, 25 (38) :4309-4312

[9] N-ACYL-TRIHALOGENACETALDIMINE ALS REAKTIVE ZWISCHENSTUFEN BEI ELIMINIERUNGS-ADDITIONS-REAKTIONEN .2. WEITERE REAKTIONEN VON 2.2.2-TRIFLUOR-1-ATHANSULFONYL-N-ACYL-ATHYLAMINEN [J].

WEYGAND, F ;

STEGLICH, W ;

LENGYEL, I ;

FRAUNBER.F .

CHEMISCHE BERICHTE-RECUEIL, 1966, 99 (06) :1932-&

[10] 2.2.2-TRIFLUORO-L-ACYLAMINO-ETHYL RESIDUES AS PROTECTIVE GROUPS FOR IMINO GROUP OF HISTIDINE IN PEPTIDE SYNTHESES [J].

WEYGAND, F ;

STEGLICH, W ;

PIETTA, P .

CHEMISCHE BERICHTE-RECUEIL, 1967, 100 (12) :3841-&