[3+2] METHYLENECYCLOPENTANE ANNULATIONS OF UNACTIVATED AND ELECTRON-RICH OLEFINS WITH 2-(PHENYLSULFONYL)-1-METHYLENECYCLOPROPANES

被引：58

作者：

SINGLETON, DA

CHURCH, KM

机构：

[1] Department of Chemistry, Texas A&M University, College Station

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 16期

关键词：

D O I：

10.1021/jo00303a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: The thiyl radical catalyzed reaction of 1 with unactivated and electron-rich olefins affords methylene-cyclopentanes regiospecifically. Using irradiation in the presence of dibutyl disulfide, these reactions can be achieved using equimolar amounts of olefins. © 1990, American Chemical Society. All rights reserved.

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页码：4780 / 4782

页数：3

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