RAPID SYNTHESIS OF 5-O-(TERT-BUTYLDIPHENYLSILYL)-2-DEOXY-L-RIBONOLACTONE

被引：10

作者：

SHARMA, R ^{[1
]}

MARQUEZ, VE ^{[1
]}

机构：

[1] NCI,DIV CANC TREATMENT,MED CHEM LAB,DEV THERAPEUT PROGRAM,BETHESDA,MD 20892

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 13期

关键词：

D O I：

10.1080/00397919408010201

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient, four-step synthesis of the title compound (1) in 21% overall yield from L-arabinose is described. Selective formation of the 2-O-phenoxythiocarbonyl derivative 6 and its tributyltin hydride/azobis(isobutyronitrile) deoxygenation performed in the presence of an unprotected hydroxyl group are highlighted.

引用

页码：1937 / 1945

页数：9

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