HYPERCOORDINATE PHOSPHORUS IN GOLD CLUSTERS - NOVEL SPECIES [P(AUL)6]3+(BF4-)3

被引：49

作者：

ZELLER, E ^{[1
]}

SCHMIDBAUR, H ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,LICHTENBERGSTR 4,W-8046 GARCHING,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 01期

关键词：

D O I：

10.1039/c39930000069

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of (Me3Si)3P with a solution of six equivalents of a (triorganophosphine)gold(I) tetrafluoroborate LAu+BF4-(L = Bu(t)3P, Pri3P) in tetrahydrofuran, in the presence of an excess of KF, leads to high yields of the title compounds la, b as stable microcrystalline solids; the products, which contain interstitial six-coordinate phosphorus, have been characterized by a detailed NMR study and on the basis of elemental and mass spectrometric analysis.

引用

页码：69 / 70

页数：2

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