REACTION OF [MO3S4(H2O)9]4+ WITH COBALT AND MERCURY - SYNTHESES AND X-RAY STRUCTURES OF DOUBLE CUBANE-TYPE CLUSTER, [(H2O)9MO3S4COCOS4MO3(H2O)9] (CH3.C6H4.SO3)8.18H2O AND SANDWICH CUBANE-TYPE CLUSTER, [(H2O)9MO3S4HGS4MO3(H2O)9] (CH3.C6H4.SO3)8-20H2O

被引：74

作者：

SHIBAHARA, T ^{[1
]}

AKASHI, H ^{[1
]}

YAMASAKI, M ^{[1
]}

HASHIMOTO, K ^{[1
]}

机构：

[1] OKAYAMA UNIV SCI, DEPT CHEM, 1-1 RIDAI CHO, OKAYAMA 700, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 04期

关键词：

D O I：

10.1246/cl.1991.689

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new clusters, [(H2O)9Mo3S4CoCoS4Mo3(H2O)9]-(Ch3.C6H4.So3)8.18H2O (1) and [(H2O)9Mo3S4HgS4Mo3(H2O)9]-(CH3.C6H4.SO3)8.20H2O (2), have been synthesized by the reaction of [Mo3S4(H2O)9]4+(3') with metallic cobalt and mercury, respectively. The X-ray structure analyses revealed that in 1 two Mo3S4Co(H2O)9 moieties are joined through two cobalt-sulfur bonds, and in 2 a mercury atom was sandwiched by two 3's.

引用

页码：689 / 692

页数：4

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