SYNTHESIS AND CHARACTERIZATION OF TELECHELIC OLIGOSILOXANES

被引:7
作者
KLEMM, E
BEIL, U
机构
[1] Friedrich-Schiller-Universität Jena, Sektion Chemie, Jena, O-6900
来源
ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1991年 / 188卷
关键词
D O I
10.1002/apmc.1991.051880117
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Photoaddition of 1,8-dimercaptooctane with 1,1,3,3-tetramethyl-1,3-divinylsiloxane leads to SH or vinyl terminated prepolymers. DC and HPLC investigations showed that the prepolymers are a mixture of oligomers with increasing chain length. The distribution depends on the molar ratio r of the monomers. Their structures are confirmed by NMR spectroscopy and elemental analysis.
引用
收藏
页码:189 / 194
页数:6
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