PI-FACIAL STEREOSELECTIVITIES IN DIELS-ALDER CYCLOADDITIONS TO A DISSYMMETRIC CYCLOHEXA-1,3-DIENE MOIETY IN A NOVEL, CAGED POLYCYCLIC FRAMEWORK

被引：13

作者：

MEHTA, G ^{[1
]}

PADMA, S ^{[1
]}

REDDY, SHK ^{[1
]}

NETHAJI, M ^{[1
]}

机构：

[1] INDIAN INST SCI,DEPT INORGAN & PHYS CHEM,BANGALORE 560012,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 15期

关键词：

D O I：

10.1039/p19940002049

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel polycyclic 1,3-dienes 4 and 5 have been synthesised and shown to undergo Diels-Alder cycloadditions exclusively from the carbonyl face. Steric environment seems to be predominantly responsible for the observed stereochemistry.

引用

页码：2049 / 2050

页数：2

共 14 条

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