HIGH-RESOLUTION DOUBLE-RESONANCE SPECTROSCOPY ON RYDBERG STATES OF CO

被引：53

作者：

DRABBELS, M ^{[1
]}

HEINZE, J ^{[1
]}

TERMEULEN, JJ ^{[1
]}

MEERTS, WL ^{[1
]}

机构：

[1] CATHOLIC UNIV NIJMEGEN,DEPT MOLEC & LASER PHYS,6525 ED NIJMEGEN,NETHERLANDS

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 08期

关键词：

D O I：

10.1063/1.465919

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Rydberg states L1PI (v = 0), L'1PI (v = 1), K1SIGMA+ (v = 0), W1PI (v = 0), and W'1PI (v = 2) have been studied in a 2 + 1 double-resonance detection scheme with a resolution of 0.005 cm-1. Accurate molecular constants have been derived for these states. From the observed linewidths of individual rotational transitions, predissociation rates for the Rydberg states have been deduced. For the first time a clear J and e/f dependence for the predissociation of CO has been observed. One of the states causing the observed predissociation could be identified as the D'1SIGMA+ state.

引用

页码：5701 / 5711

页数：11

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