CONICAL INTERSECTIONS AND THE MECHANISM OF SINGLET PHOTOREACTIONS

被引：151

作者：

KLESSINGER, M

机构：

[1] Organisch-Chemisches Institut, Universität Münster, D-48149

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 05期

关键词：

AB INITIO CALCULATIONS; CONICAL INTERSECTION; DIRADICALOID; PERICYCLIC REACTIONS; PHOTOCHEMISTRY;

D O I：

10.1002/anie.199505491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In contrast to the previously accepted theoretical model, the reaction funnel of a nonadiabatic photoreaction, which has similar significance as the transition state of a thermal reaction, is a real conical intersection (CI) at geometries of low symmetry. This is shown schematically on the right. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：549 / 551

页数：3

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