ADDUCTS OF METHYLZINC TERT-BUTYLTHIOLATE AND NITROGENOUS BASES - IMPLICATIONS FOR THE USE OF ADDUCTS IN MOCVD

被引：19

作者：

MALIK, MA ^{[1
]}

MOTEVALLI, M ^{[1
]}

WALSH, JR ^{[1
]}

OBRIEN, P ^{[1
]}

JONES, AC ^{[1
]}

机构：

[1] EPICHEM LTD,WIRRAL L62 3QF,MERSEYSIDE,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 05期

关键词：

D O I：

10.1039/jm9950500731

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Stable adducts are formed by the interaction of the pentameric compound [CH(3)ZnSBu(t)](5) with nitrogenous bases such as pyridine and 1,3,5-trimethylhexahydro-1,3,5-triazine. The X-ray single-crystal structures are reported for the pyridine and triazine compounds. The triazine compound exists, in the solid state, in two distinct forms differing in the relative orientation of the methyl group at the nitrogen atoms. The adducts are all dimers with ZnCS2N coordination at the metal ion. The chemistry of these compounds is discussed in relation to the deposition of II/VI materials such as ZnS by MOCVD.

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页码：731 / 736

页数：6

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