Solvent-controlled addition of alkynyltins or allylic tins to aldehydes catalyzed by indium trichloride

被引：59

作者：

Yasuda, M

Miyai, T

Shibata, I

Baba, A

Nomura, R

Matsuda, H

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

[2] OSAKA INST TECHNOL,DEPT APPL CHEM,ASAHI,OSAKA 535,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 52期

关键词：

D O I：

10.1016/0040-4039(95)02057-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Indium trichloride promoted catalytically. the addition of alkynyltins or allylic tins to aldehydes in two ways: transmetallation with the tin compounds and activation of aldehydes as a Lewis acid. The stereochemical outcome in the addition of cinnamyltributyltin to an aldehyde strongly indicates that control of the process can be achieved simply by the choice of solvent acetonitrile or dichloromethane.

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页码：9497 / 9500

页数：4

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