NUCLEOPHILIC-SUBSTITUTION REACTIONS OF SPIN ADDUCTS - IMPLICATIONS FOR THE CORRECT IDENTIFICATION OF REACTION INTERMEDIATES BY EPR SPIN TRAPPING

被引：103

作者：

DAVIES, MJ

GILBERT, BC

STELL, JK

WHITWOOD, AC

机构：

[1] Department of Chemistry, University of York, Heslington

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 03期

关键词：

D O I：

10.1039/p29920000333

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radical adducts to nitrone spin traps have been shown, in aqueous solution, to undergo conversion to the hydroxyl radical adduct via nucleophilic substitution reactions; these observations have important consequences for the interpretation of data from EPR/spin-trapping experiments.

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页码：333 / 335

页数：3

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