CATIONIC POLYMERIZATION OF ISOBUTYL VINYL ETHER INITIATED WITH THE SYSTEM ALUMINUM TRICHLORIDE ETHYL-ACETATE, IN TOLUENE SOLUTION

被引：10

作者：

LELEU, JM ^{[1
]}

TARDI, M ^{[1
]}

POLTON, A ^{[1
]}

SIGWALT, P ^{[1
]}

机构：

[1] UNIV PARIS 06,CHIM MACROMOLEC LAB,UA 24,4 PL JUSSIEU,F-75230 PARIS 05,FRANCE

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1991年 / 47卷

关键词：

D O I：

10.1002/masy.19910470120

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The cationic polymerization of isobutyl vinyl ether initiated with the title system apparently has some features of a living polymerization (linear increase of number average molecular weight M(n)BAR with conversion). However, evidence is given for the occurrence of a transfer reaction resulting in the increase of the number of macromolecules, and this even for relatively low molecular weights.

引用

页码：253 / 262

页数：10

共 7 条

[1]

AOSHIMA S, 1986, POLYM BULL, V15, P417

[2]

FAUST R, 1986, POLYM BULL, V15, P317

[3] RECENT DEVELOPMENTS IN LIVING CARBOCATIONIC POLYMERIZATION OF ALKENES [J].

KENNEDY, JP .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1990, 32 :119-129

[4] LIVING CATIONIC POLYMERIZATION OF VINYL MONOMERS BY ORGANO-ALUMINUM HALIDES .4. POLYMERIZATION OF ISOBUTYL VINYL ETHER BY ETALCL2 IN THE PRESENCE OF ETHER ADDITIVES [J].

KISHIMOTO, Y ;

AOSHIMA, S ;

HIGASHIMURA, T .

MACROMOLECULES, 1989, 22 (10) :3877-3882

[5] POLYMERIZATION OF STYRENE BY PERCHLORIC ACID [J].

PEPPER, DC ;

REILLY, PJ .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1966, 291 (1424) :41-&

[6] DESIGN AND INITIATORS OF LIVING CATIONIC POLYMERIZATION OF VINYL MONOMERS [J].

SAWAMOTO, M ;

HIGASHIMURA, T .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1990, 32 :131-144

[7]

TAZI M, 1987, BR POLYM J, V19, P369

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