SYNTHESIS AND MESOMORPHISM OF NICKEL, PALLADIUM AND ZINC-COMPLEXES OF LATERALLY FLUORINATED ALKOXYDITHIOBENZOATES

被引：14

作者：

BRUCE, DW

DHILLON, R

DUNMUR, DA

MAITLIS, PM

机构：

[1] Department of Chemistry, The University

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1992年 / 2卷 / 01期

关键词：

LIQUID CRYSTAL; ALKOXYDITHIOBENZOATE; METALLOMESOGEN; FLUORINATION;

D O I：

10.1039/jm9920200065

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis and mesomorphism of a series of 4-alkoxy-3-fluorodithiobenzoates of Ni(II), Pd(II) and Zn(II) are described. For nickel and palladium, fluorination promoted the smectic C phase at the expense of the nematic phase. In the case of nickel, mesomorphic ranges were slightly reduced, but they were increased in the palladium complexes.

引用

收藏

页码：65 / 69

页数：5

相关论文

共 14 条

[1] SYNTHESIS AND PHASE-BEHAVIOR OF MESOMORPHIC TRANSITION-METAL COMPLEXES OF ALKOXYDITHIOBENZOATES - CRYSTAL AND MOLECULAR-STRUCTURE OF 3 METAL ALKOXYDITHIOBENZOATES [J].

ADAMS, H ;

ALBENIZ, AC ;

BAILEY, NA ;

BRUCE, DW ;

CHERODIAN, AS ;

DHILLON, R ;

DUNMUR, DA ;

ESPINET, P ;

FEIJOO, JL ;

LALINDE, E ;

MAITLIS, PM ;

RICHARDSON, RM ;

UNGAR, G .

JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (05) :843-855

[2] Carbithioic acid studies. I. Tolyl-4-carbithioic acid and certain derivatives [J].

Bost, RW ;

Mattox, WJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1930, 52 :332-335

[3] LINEAR DICHROISM OF MESOMORPHIC TRANSITION-METAL COMPLEXES OF ALKOXYDITHIOBENZOATES [J].

BRUCE, DW ;

DUNMUR, DA ;

HUNT, SE ;

MAITLIS, PM ;

ORR, R .

JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (05) :857-861

[4] SYNTHESES OF NEMATOGEN COPPER-COMPLEXES USING HALOGEN SUBSTITUTED LIGANDS [J].

BUI, E ;

BAYLE, JP ;

PEREZ, F ;

LIEBERT, L ;

COURTIEU, J .

LIQUID CRYSTALS, 1990, 8 (04) :513-526

[5] THE EFFECT OF LATERAL SUBSTITUTION ON SMECTIC C-FORMATION [J].

COATES, D .

LIQUID CRYSTALS, 1987, 2 (04) :423-428

[6]

DHILLON R, 1991, THESIS U SHEFFIELD

[7] SULFUR CHELATES .15. SULFUR ADDITION AND ABSTRACTION REACTIONS OF DITHIOARYL ACID COMPLEXES OF ZINC(II), NICKEL(II), PALLADIUM(II), AND PLATINUM(II) AND X-RAY CRYSTAL-STRUCTURES OF BIS(TRITHIOPEROXYCUMATO)ZINC(II) AND DITHIOCUMATO (TRITHIOPEROXYCUMATO)NICKEL(II) [J].

FACKLER, JP ;

FETCHIN, JA ;

FRIES, DC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (21) :7323-&

[8] SULFUR CHELATES .8. OXIDATIVE ADDITION OF SULFUR TO DITHIOARYL ACID COMPLEXES OF NICKEL(2) AND ZINC(2) [J].

FACKLER, JP ;

COUCOUVA.D ;

FETCHIN, JA ;

SEIDEL, WC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (11) :2784-+

[9] The Synthesis of Several Lateral Difluoro-substituted 4,4 ''-Dialkyl- and 4,4 ''-Alkoxyalkyl-Terphenyls and a Rationalisation of the Effect of Such Substitution on Mesophase Type and Transition Temperatures? [J].

Gray, G. W. ;

Hird, M. ;

Toyne, K. J. .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1991, 204 :43-64

[10] INFARED INVESTIGATION OF AROMATIC AND ALIPHATIC DITHIOACIDS AS LIGANDS .1. METAL DITHIOBENZOATES [J].

MALTESE, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (23) :2664-2667