A NEW AND EFFICIENT SYNTHESIS OF ENAMIDO DIENES AND DIENAMIDO OLEFINS FOR INTRAMOLECULAR DIELS-ALDER ADDITIONS LEADING TO HYDROQUINOLONES AND ALKALOIDS

被引：9

作者：

CHOCKALINGAM, K ^{[1
]}

HARIRCHIAN, B ^{[1
]}

BAULD, NL ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 02期

关键词：

D O I：

10.1080/00397919008052283

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

efficiently introduced into a bifunctional or more general context by alkylation of the previously unreported enolates of enamides or dienamides. These alkylations provide an extremely convenient method for the synthesis of bifunctional enamido dienes and dienamido olefins, both of which are readily converted to hydroquinolones by intramolecular Diels-Alder cycloaddition. The enamido or dienamido functionality is directly and. Copyright © 1990 by Taylor & Francis Group. All rights reserved.

引用

页码：189 / 202

页数：14

共 9 条

[1]

A STRATEGY FOR INTERMOLECULAR DIELS-ALDER CYCLO-ADDITION TO ENAMIDES [J].