BINDING OF CUPRIC ION BY CROSSLINKED POLYETHYLENIMINE

被引：5

作者：

TAKAGISHI, T ^{[1
]}

OKUDA, S ^{[1
]}

KUROKI, N ^{[1
]}

KOZUKA, H ^{[1
]}

机构：

[1] HIROSHIMA BUNKYO WOMENS COLL,ASAKITAKU,HIROSHIMA 73102,JAPAN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1985年 / 23卷 / 11期

关键词：

COPPER COMPOUNDS - Chemical Reactions - METALLORGANIC POLYMERS - Synthesis;

D O I：

10.1002/pol.1985.170231115

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Complex formation between copper(II) and polyethylenimine (PEI) which is bridged by reaction with the bifunctional crosslinkers, dichloroethane and glutaraldehyde and involves various degrees of crosslinkage has been studied at 25 degree C in an aqueous solution. The effect of crosslinking on the extent of complexation with the metal ion is presented. PEIs and laurylated PEI (6. 4% of its residues were alkylated) with various degrees of crosslinkage are used in the study.

引用

页码：2875 / 2878

页数：4

共 14 条

[1]

DAVIS LE, 1968, WATER SOLUBLE RESINS, P216

[2] CONCENTRATION AND SEPARATION OF TRACE METAL CATIONS BY COMPLEXATION ON POLYAMINE-POLYUREA RESINS [J].

DINGMAN, J ;

HISCOCK, KB ;

SIGGIA, S ;

BARTON, C .

ANALYTICAL CHEMISTRY, 1972, 44 (08) :1351-&

[3] METAL-POLYELECTROLYTE COMPLEXES .1. THE POLYACRYLIC ACID-COPPER COMPLEX [J].

GREGOR, HP ;

LUTTINGER, LB ;

LOEBL, EM .

JOURNAL OF PHYSICAL CHEMISTRY, 1955, 59 (01) :34-39

[4] METAL-POLYELECTROLYTE COMPLEXES .2. COMPLEXES OF COPPER WITH CROSS-LINKED POLYACRYLIC AND POLYMETHACRYLIC ACIDS [J].

GREGOR, HP ;

LUTTINGER, LB ;

LOEBL, EM .

JOURNAL OF PHYSICAL CHEMISTRY, 1955, 59 (04) :366-368

[5] INTERACTION OF CROSS-LINKED POLYMETHACRYLIC ACID WITH POLYVALENT METAL IONS [J].

GUSTAFSON, RL ;

LIRIO, JA .

JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (09) :2849-+

[6] BINDING OF DIVALENT METAL IONS BY CROSS-LINKED POLYACRYLIC ACID [J].

GUSTAFSON, RL ;

LIRIO, JA .

JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (05) :1502-+

[7] PREPARATION AND CHARACTERIZATION OF SOME DERIVATIVES OF POLY(ETHYLENIMINE) [J].

JOHNSON, TW ;

KLOTZ, IM .

MACROMOLECULES, 1974, 7 (02) :149-153

[8] STRUCTURE-VOLUME RELATIONSHIPS - SINGULAR VOLUME EFFECTS PRODUCED BY CUPRIC ION-GLOBULAR PROTEIN-INTERACTION [J].

KATZ, S ;

SHINABERRY, RG ;

HECK, EL ;

SQUIRE, W .

BIOCHEMISTRY, 1980, 19 (16) :3805-3813

[9] POLYVALENT ANION-EXCHANGE RESINS COMPOSED OF CROSS-LINKED POLYETHYLENIMINE COMPLEXES OF HEAVY METALS [J].

NONOGAKI, S ;

MAKISHIMA, S ;

YONEDA, Y .

JOURNAL OF PHYSICAL CHEMISTRY, 1958, 62 (05) :601-603

[10] STUDIES OF A CROSS-LINKED POLY(ETHYLENEIMINE) ION-EXCHANGE RESIN [J].

SHEPHERD, EJ ;

KITCHENER, JA .

JOURNAL OF THE CHEMICAL SOCIETY, 1957, (JAN) :86-92

← 1 2 →