SYNTHESIS AND STRUCTURE OF 1,10-ORTHO-BENZENO[2.2]ORTHOCYCLOPHANE-5,6,12,15-DIQUINONE - AN EXPERIMENTAL-EVIDENCE FOR ATTRACTIVE INTERACTION BETWEEN ORTHO-BENZOQUINONE AND PARA-BENZOQUINONE

被引：6

作者：

FUKAZAWA, Y

NAKAMURA, T

USUI, S

机构：

[1] Department of Chemistry, Faculty of Science, Hiroshima University, Hiroshima

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(00)79717-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound (2) was synthesized by cycloaddition of 4,5-dimethoxybenzocyclobutene and 1,4-diacetoxyanthracene and subsequent hydrolysis followed by oxidations. The syn conformer of 2 was proven to be more stable than anti implying that through space interaction between o- and p-benzoquinone is attractive.

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页码：3183 / 3186

页数：4

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