THEORETICAL COMPARISON BETWEEN NUCLEOPHILIC AND ELECTROPHILIC TRANSITION-METAL CARBENES USING GENERALIZED MOLECULAR-ORBITAL AND CONFIGURATION-INTERACTION METHODS

被引：112

作者：

TAYLOR, TE ^{[1
]}

HALL, MB ^{[1
]}

机构：

[1] TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1984年 / 106卷 / 06期

关键词：

D O I：

10.1021/ja00318a007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1576 / 1584

页数：9

共 56 条

[1]

ARENSEN SP, 1966, ACTA CHEM SCAND, V20, P2711

[2]

BAIRD NC, 1978, J AM CHEM SOC, V100, P1333, DOI 10.1021/ja00473a001

[3] BOND ENERGIES [J].

BENSON, SW .

JOURNAL OF CHEMICAL EDUCATION, 1965, 42 (09) :502-&

[4] MO CALCULATIONS ON METAL CARBENE COMPLEXES AND METAL ACYL COMPLEXES - IMPORTANCE OF LUMO IN DETERMINING SITE OF NUCLEOPHILIC-ATTACK [J].

BLOCK, TF ;

FENSKE, RF ;

CASEY, CP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (02) :441-443

[5] PHOTOELECTRON SPECTROSCOPIC STUDY OF SOME PENTACARBONYLCHROMIUM CARBENE COMPLEXES [J].

BLOCK, TF ;

FENSKE, RF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (13) :4321-4330

[6] APPROXIMATE MOLECULAR-ORBITAL CALCULATIONS ON CARBENE LIGANDS AND COMPLEXES - ABILITY OF CARBENE LIGANDS TO ACT AS SIGMA DONORS AND PI ACCEPTORS [J].

BLOCK, TF ;

FENSKE, RF .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 139 (02) :235-269

[7] REACTIONS OF ETA5-C5H5(CO)2FECHC6H5+ WITH ALKENES AND ALKYNES - OBSERVATION OF EFFICIENT BENZYLIDENE-TRANSFER REACTIONS [J].

BROOKHART, M ;

HUMPHREY, MB ;

KRATZER, HJ ;

NELSON, GO .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (26) :7802-7803

[8] FACILE SYNTHESIS, SPECTRAL CHARACTERIZATION, AND ETHYLIDENE TRANSFER-REACTIONS OF COMPLEXES OF THE TYPE CP(CO)(L)FE=CHCH3+ [J].

BROOKHART, M ;

TUCKER, JR ;

HUSK, GR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (04) :979-981

[9] CHEMISTRY OF TRANSITION-METAL CARBENE COMPLEXES AND THEIR ROLE AS REACTION INTERMEDIATES [J].

CARDIN, DJ ;

CETINKAY.B ;

DOYLE, MJ ;

LAPPERT, MF .

CHEMICAL SOCIETY REVIEWS, 1973, 2 (01) :99-144

[10] REACTIONS OF (CO)5WCHC6H5 WITH ALKENES [J].

CASEY, CP ;

POLICHNOWSKI, SW ;

SHUSTERMAN, AJ ;

JONES, CR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (24) :7282-7292

← 1 2 3 4 5 6 →