FORMATION OF COMPLEXES WITH C ... H ... MN INTERACTIONS FROM REACTIONS OF DIENES OR ACETYLENE WITH A MU-HYDRIDO HETEROMETALLIC DIMER - X-RAY CRYSTAL-STRUCTURES OF [(ETA-5C5H5)MOMN(MU-H)(MU-PPH2)(CO)6], [(ETA-5C5H5)MOMN(MU-SIGMA-ETA-3-CH2C(ME)CHME)-(MU-PPH2)(CO)4], AND [(ETA-5C5H5)MOMN(MU-SIGMA-ETA-4-CHCHCH2CHPPH2)(CO)4]T

被引：56

作者：

HORTON, AD ^{[1
]}

MAYS, MJ ^{[1
]}

RAITHBY, PR ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1985年 / 05期

关键词：

D O I：

10.1039/c39850000247

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：247 / 250

页数：4

共 12 条

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[7]

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[8] STEPWISE TRANSFORMATION OF A TERMINALLY BOUND ALKYLIDYNE LIGAND TO A BRIDGING ACYL GROUP AT A BIMETAL CENTER VIA AN ASYMMETRICALLY BRIDGING ALKYL - X-RAY CRYSTAL-STRUCTURES OF [N(PPH3)2][REW(MU-CHR)(CO)9] (R = C6H4ME-4), [REW(MU-CH2R)(MU-ME2PCH2PME2)(CO)7], AND [REW(MU-OCCH2R)(MU-PH2PCH2PPH2)(CO)6(P(OME)3)]NG [J].

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[10] CHEMISTRY OF DI-METAL AND TRI-METAL COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .23. ALKYNE INSERTION INTO HETERONUCLEAR DIMETAL COMPOUNDS WITH BRIDGING TOLYLMETHYLIDYNE LIGANDS - CRYSTAL-STRUCTURES OF [FEW(MU-C(C6H4ME-4)C(ME)C(ME))(CO)5(ETA-C5H5)] AND [FE2W(MU-3-CC6H4ME-4)(MU-ME3SIC2SIME3)(MU-CO)(CO)6(ETA-C5H5)] [J].

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