TEMPERATURE-DEPENDENCE OF CONDUCTIVITY OF MIXED-PHASE COMPOSITE POLYMER SOLID ELECTROLYTES

被引：68

作者：

WIECZOREK, W

机构：

[1] Institute of Solid State Technology, Department of Chemistry, Warsaw University of Technology, 00-664 Warszawa

来源：

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 1992年 / 15卷 / 02期

关键词：

D O I：

10.1016/0921-5107(92)90041-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

This paper describes the conductivity data obtained for various polymeric electrolytes containing dispersed inorganic and organic fillers. For all of the systems studied an increase in ambient temperature conductivity in comparison with pristine poly(ethylene oxide)-based electrolytes was achieved. The temperature dependence of the conductivity data can be described by the Arrhenius equation below and above the melting point of the polymer crystalline phase. The relationship between the conductivity pre-exponential factor and the activation energy is discussed according to the Meyer-Neldel rule.

引用

页码：108 / 114

页数：7

共 20 条

[1] THE ACTIVATION ENTROPY FOR TRANSPORT IN IONIC CONDUCTORS
ALMOND, DP
WEST, AR
[J]. SOLID STATE IONICS, 1987, 23 (1-2) : 27 - 35
[2] ENTROPY EFFECTS IN IONIC-CONDUCTIVITY
ALMOND, DP
WEST, AR
[J]. SOLID STATE IONICS, 1986, 18-9 : 1105 - 1109
[3] PROPERTIES AND APPLICATIONS OF LITHIUM ION-CONDUCTING POLYMERS
CROCE, F
PASSERINI, S
SELVAGGI, A
SCROSATI, B
[J]. SOLID STATE IONICS, 1990, 40-1 : 375 - 379
[4] PROPERTIES OF MIXED POLYMER AND CRYSTALLINE IONIC CONDUCTORS
CROCE, F
BONINO, F
PANERO, S
SCROSATI, B
[J]. PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1989, 59 (01): : 161 - 168
[5] FREQUENCY FACTOR AND ACTIVATION ENERGY FOR THE VOLUME DIFFUSION OF METALS
DIENES, GJ
[J]. JOURNAL OF APPLIED PHYSICS, 1950, 21 (11) : 1189 - 1192
[6] APPLICABILITY OF THE MEYER-NELDEL RULE TO SELECTED SINGLE-CRYSTAL, CERAMIC AND GLASSY SUPERIONIC CONDUCTORS
GARBARCZYK, J
KUREK, P
NOWINSKI, J
JAKUBOWSKI, W
[J]. SOLID STATE IONICS, 1989, 36 (3-4) : 239 - 241
[7] He Y, 1986, CHEM J CHINESE U, V2, P97
[8] SURVEY AND INTERPRETATION OF PRE-EXPONENTIALS OF CONDUCTIVITY
NOWICK, AS
LEE, WK
JAIN, H
[J]. SOLID STATE IONICS, 1988, 28 : 89 - 94
[9] MIXED SOLID ELECTROLYTES BASED ON POLY(ETHYLENE OXIDE)
PLOCHARSKI, J
WIECZOREK, W
PRZYLUSKI, J
SUCH, K
[J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1989, 49 (01): : 55 - 60
[10] PEO based composite solid electrolyte containing NASICON
Plocharski, J.
Wieczorek, W.
[J]. Solid State Ionics, 1988, 28-30 : 979 - 982

← 1 2 →