RATE CONSTANTS FOR VIBRATIONAL TRANSITIONS IN HYDROGEN AND ISOTOPES

被引：13

作者：

KOLESNICK, RE

BILLING, GD

机构：

[1] Department of Chemistry, H.C. Ørsted Institute, University of Copenhagen

来源：

CHEMICAL PHYSICS | 1993年 / 170卷 / 02期

关键词：

D O I：

10.1016/0301-0104(93)80065-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rate constants for V-V and V-T/R transitions in hydrogen and its isotopes have been computed using a recent ab initio surface. The results are compared with experimental data as well as with previous calculations using a simplified dumbbell type potential.

引用

收藏

页码：201 / 207

页数：7

相关论文

共 16 条

[1] VIBRATIONAL-RELAXATION OF ORTHO AND PARA-H2 IN RANGE 400-50K [J].

AUDIBERT, MM ;

VILASECA, R ;

LUKASIK, J ;

DUCUING, J .

CHEMICAL PHYSICS LETTERS, 1975, 31 (02) :232-236

[2] EXPERIMENTAL STUDY OF VIBRATIONAL-RELAXATION OF ORTHO AND PARA-H2 IN COLLISIONS WITH HE-4 IN RANGE 300-50-K [J].

AUDIBERT, MM ;

VILASECA, R ;

LUKASIK, J ;

DUCUING, J .

CHEMICAL PHYSICS LETTERS, 1976, 37 (03) :408-411

[3] EXPERIMENTAL-STUDY OF THE VIBRATIONAL-RELAXATION OF HD IN COLLISION WITH HD AND HE-4 IN THE RANGE 80-400-K [J].

BARROUX, C ;

AUDIBERT, MM .

CHEMICAL PHYSICS LETTERS, 1979, 66 (03) :483-486

[4] COMPARISON OF QUANTUM-MECHANICAL AND SEMICLASSICAL CROSS-SECTIONS AND RATE CONSTANTS FOR VIBRATIONAL-RELAXATION OF N-2 AND CO COLLIDING WITH HE-4 [J].

BILLING, GD .

CHEMICAL PHYSICS, 1986, 107 (01) :39-46

[5]

BILLING GD, 1978, CHEM PHYS, V30, P387, DOI 10.1016/0301-0104(78)87010-4

[6]

BILLING GD, 1984, COMPUT PHYS REP, V1, P237, DOI 10.1016/0167-7977(84)90006-6

[7] VIBRATIONAL ENERGY EXCHANGE BETWEEN H2(V=1) AND D2, N2, HCL, AND CO2 [J].

BOTT, JF .

JOURNAL OF CHEMICAL PHYSICS, 1976, 65 (10) :3921-3928

[8] STATE-TO-STATE VIBRATION TRANSLATION AND VIBRATION VIBRATION RATE CONSTANTS IN H2-H2 AND HD-HD COLLISIONS [J].

CACCIATORE, M ;

BILLING, GD .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (01) :217-223

[9] VIBRATION-TO-TRANSLATION ENERGY EXCHANGES IN H-2 COLLIDING WITH HIGHLY VIBRATIONALLY EXCITED H-2-MOLECULES [J].

CACCIATORE, M ;

CAPITELLI, M ;

BILLING, GD .

CHEMICAL PHYSICS LETTERS, 1989, 157 (04) :305-308

[10] RAMAN PUMP PROBE MEASUREMENTS OF STATE-TO-STATE ENERGY-TRANSFER RATES IN THE V=1 STATE OF H2 [J].

FARROW, RL ;

CHANDLER, DW .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (04) :1994-1998