SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF SEVERAL UNUSUAL TRINUCLEAR CLUSTERS CONTAINING EITHER RHODIUM OR COBALT AND THE CYCLOPENTADIENYL OR PENTAMETHYLCYCLOPENTADIENYL LIGANDS

被引：13

作者：

BARNES, CE

DIAL, MR

机构：

来源：

ORGANOMETALLICS | 1988年 / 7卷 / 03期

关键词：

D O I：

10.1021/om00093a036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：782 / 784

页数：3

共 37 条

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[3] ELECTROCHEMICAL ANALYSIS OF BICAPPED TRIANGULAR COBALT CYCLOPENTADIENYL CLUSTERS, [CO3(ETA-5-C5H5-XMEX)3(MU-3-X)(MU-3-Y)]N(X = 0, 1, 5), CONTAINING MIXED PI-ACCEPTOR-X AND PI-DONOR-Y CAPPING LIGANDS (X = CO, NO-Y = NSIME3, NC(O)NH2,NH) - PRONOUNCED VARIATIONS IN REDOX BEHAVIOR AS A FUNCTION OF COORDINATING LIGANDS [J].

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[6] THE CRYSTAL-STRUCTURE OF [RH3(MU-3-CO)2(ETA-C5ME5)3] AND REACTIONS OF THE UNSATURATED METAL-CLUSTERS [MM'2(MU-3-CO)2(ETA-C5ME5)3] (M=M'=RH - M=CO OR IR, M'=RH) WITH HYDROGEN [J].

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[7] BIS(ETHYLENE)(ETA-PENTAMETHYLCYCLOPENTADIENYL)COBALT AS A PRECURSOR TO HETERONUCLEAR METAL-CLUSTERS - X-RAY CRYSTAL-STRUCTURE OF [CO2MO2(MU-CO)3(MU4-CO) (ETA-C5H5)2(ETA-C5ME5)2] - A MODEL FOR CO ACTIVATION ON A STEPPED METAL-SURFACE [J].

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[8] SYNTHESIS AND STEREOCHEMICAL ANALYSIS OF THE TRIANGULAR COBALT-DINICKEL CLUSTERS (ETA-5-C5H5-NMEN)CONI2(ETA-5-C5H5)2(MU3-CO)2 (WHERE N= 0, 1, 5) - DIRECT EVIDENCE FOR THE ANTI-BONDING TRIMETAL CHARACTER OF THE UNPAIRED ELECTRON IN THE FISCHER-PALM NI3(ETA-5-C5H5)3(MU-3-CO)2 AND RESULTING GEOMETRICAL EFFECTS UPON FORMAL OXIDATION BY REPLACEMENT OF A NICKEL WITH A COBALT ATOM [J].

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[9] PENTAMETHYLCYCLOPENTADIENYLCOPPER - A METAL-LIGAND FRAGMENT ISOLOBAL WITH METHYLENE [J].

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[10] CHEMISTRY OF DI-METAL AND TRI-METAL COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .24. COMPLEXES OF THE PENTAMETHYLCYCLOPENTADIENYLCOPPER GROUP AND THE CRYSTAL-STRUCTURES OF THE COMPOUNDS [CUPTW(MU-3-CC6H4ME-4)(CO)2(PME3)2(ETA-C5H5)(ETA-C5ME5)] AND [CURH2(MU-CO)2(ETA-C5ME5)3] [J].

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