ELECTROCATALYTIC OXIDATION OF THIOLS ON A TEMPO MODIFIED ELECTRODE

被引：44

作者：

KASHIWAGI, Y ^{[1
]}

OHSAWA, A ^{[1
]}

OSA, T ^{[1
]}

MA, Z ^{[1
]}

BOBBITT, JM ^{[1
]}

机构：

[1] UNIV CONNECTICUT, DEPT CHEM, STORRS, CT 06269 USA

来源：

CHEMISTRY LETTERS | 1991年 / 04期

关键词：

D O I：

10.1246/cl.1991.581

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Monothiols were oxidized efficiently and quantitatively to disulfides on graphite felt electrode coated with 4-amino-2,2,6,6-tetramethylpiperidinyl-1-oxyl (4-amino-TEMPO). The 4-amino-TEMPO was immobilized through an amide linkage with poly(acrylic acid). The poly(acrylic acid) was cross-linked with 1,6-diaminohexane, and the residual carboxyl groups were methylated with diazomethane. The electrode was stable and could be used repeatedly.

引用

页码：581 / 584

页数：4

共 10 条

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