HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC DETERMINATION OF OPTICAL PURITY OF PLANAR CHIRAL ORGANOMETALLIC COMPOUNDS RESOLVED BY ENZYMATIC TRANSFORMATIONS

被引：17

作者：

YAMAZAKI, Y

MOROHASHI, N

HOSONO, K

机构：

[1] Fermentation Research Institute, Agency of Industrial Science and Technology, Tsukuba, Ibaraki, 305

来源：

JOURNAL OF CHROMATOGRAPHY | 1991年 / 542卷 / 01期

关键词：

D O I：

10.1016/S0021-9673(01)88753-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The enantiomers of planar chiral organometallic compounds, i.e., 1-hydroxymethyl-2-methyl, 1-acetoxymethyl-2-methyl and 1-methoxycarbonyl-2-methyl derivatives of (eta-6-benzene)tricarbonylchromium, tricarbonyl(eta-5-cyclopentadienyl)manganese and ferrocene, and their 3-methyl analogues, were separated by high-performance liquid chromatography with a Chiralcel OD column. This method was useful to determine the optical purity for the above compounds formed in enzymic transformations.

引用

页码：129 / 136

页数：8

共 22 条

[1] ENZYMATIC RESOLUTION OF A CHIRAL ORGANOMETALLIC ESTER - ENANTIOSELECTIVE HYDROLYSIS OF 2-ETHOXYCARBONYLBUTA-1,3-DIENETRICARBONYLIRON BY PIG-LIVER ESTERASE
ALCOCK, NW
CROUT, DHG
HENDERSON, CM
THOMAS, SE
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (11) : 746 - 747
[2] SEPARATION OF METALLOCENE ENANTIOMERS BY LIQUID-CHROMATOGRAPHY - CHIRAL RECOGNITION VIA CYCLODEXTRIN BONDED PHASES
ARMSTRONG, DW
DEMOND, W
CZECH, BP
[J]. ANALYTICAL CHEMISTRY, 1985, 57 (02) : 481 - 484
[3] ELABORATION OF ALPHA-SUBSTITUTED BENZYL ALKYL ETHERS AND SULFIDES BY SUPPRESSION OF THE WITTIG AND RELATED REARRANGEMENTS VIA COMPLEXATION TO TRICARBONYLCHROMIUM
BLAGG, J
DAVIES, SG
HOLMAN, NJ
LAUGHTON, CA
MOBBS, BE
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (09): : 1581 - 1589
[4] APPLICATIONS OF HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY TO METAL-CARBONYL AND CLUSTER CHEMISTRY
CASOLI, A
MANGIA, A
PREDIERI, G
SAPPA, E
VOLANTE, M
[J]. CHEMICAL REVIEWS, 1989, 89 (02) : 407 - 418
[5] GENERAL-ASPECTS AND OPTIMIZATION OF ENANTIOSELECTIVE BIOCATALYSIS IN ORGANIC-SOLVENTS - THE USE OF LIPASES
CHEN, CS
SIH, CJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (06): : 695 - 707
[6] EBERHARDT R, 1974, TETRAHEDRON LETT, P4365
[7] STEREOCHEMISTRY OF METALLOCENES .13. OPTICALLY ACTIVE DERIVATIVES OF METHYLCYMANTRENE - PREPARATION OPTICAL ROTATORY DISPERSION AND CONFIGURATIVE CORRELATIONS
GOWAL, H
SCHLOGL, K
[J]. MONATSHEFTE FUR CHEMIE, 1967, 98 (06): : 2302 - &
[8] TRIS (4-TERT-BUTYLPHENYLCARBAMATE)S OF CELLULOSE AND AMYLOSE AS USEFUL CHIRAL STATIONARY PHASES FOR CHROMATOGRAPHIC OPTICAL RESOLUTION
OKAMOTO, Y
HATANO, K
ABURATANI, R
HATADA, K
[J]. CHEMISTRY LETTERS, 1989, (05) : 715 - 718
[9] CHROMATOGRAPHIC RESOLUTION .11. CONTROLLED CHIRAL RECOGNITION OF CELLULOSE TRIPHENYLCARBAMATE DERIVATIVES SUPPORTED ON SILICA-GEL
OKAMOTO, Y
KAWASHIMA, M
HATADA, K
[J]. JOURNAL OF CHROMATOGRAPHY, 1986, 363 (02): : 173 - 186
[10] STEREOCHEMISTRY OF METALLOCENES - 20 YEARS OF PROGRESS AND RECENT ADVANCES
SCHLOGL, K
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 300 (1-2) : 219 - 248

← 1 2 3 →